Jolie has been typed ISTp as long as I remember. Only other type I have seen really is INFp. About Pitt...I have seen types from ENTj to ESTp to ENFp to ISTp and probably more. I have no strong personal opinion as I only know them from movies and VI but imho Jolie seems the introvert and Brad the extrovert. Jolie also seems at least decent with Si. Hard to say anything for sure based on so little evidence.